Okay, what frosty suggested was great, but I have something that may be quicker. It won't be true chrome ( what spray paint is? ) but it will be a very fine, shiny silver.
First off, you NEED primer. It isn't even an option, really. My preferred primer is Krylon "Ruddy Brown " Primer...mostly because it dries to the touch in about 15 minutes, and you can find it at Walmart. I would say leave it for about 2-3 hours to cure somewhat, and then go over it with a very fine sanding sponge just to get rid of any paint dusting that may have occurred. ( The fine sanding is optional, but I highly suggest it )
http://farm4.staticflickr.com/3794/9395038651_f2de3f18f2_c.jpg
Next, spray on the gloss black! I use Krylon Gloss black....the key here is to spray on 1 or 2 heavier coats, but be wary of drips. The shinier your base coat, the shinier your top chrome coat. Leave this for an hour untouched.
And lastly, The silver. I use Rustoleum Premium metallic Titanium Silver. It is my favourite paint for my Thomas helmets. It looks like this.
http://www.amazon.ca/Rust-Oleum-245220-Universal-Titanium-Metallic/dp/B0016H2KLS
I understand that it is not particularly shiny...it's more of a matte silver....but it is super durable. Most chrome paints fingerprint or rub off, but not this paint. I suggest three light coats over the course of am hour....about every 20 minutes or so.
If done right, your helmet could come out looking like this. Not chrome, obviously, but still pretty sexy to me!
http://farm8.staticflickr.com/7453/9534115906_c259d361ef_c.jpg
http://farm6.staticflickr.com/5546/9533692368_fa4fb3eeab_c.jpg
Hope this helps.